16. When n+l has the same value for two or more orbitals,the new electron enters the orbital where
(a) n is maximum
(b) n is minimum
(c) l is maximum
(d) l is minimum
Ans. (b)
17. A balloon filled with ethylene is pricked with a sharp pointed needle and quickly placed in a tank
full of hydrogen at the same pressure. After a while the balloon would have
(a) Shrunk
(b) Enlarged
(c) Completely collapsed
(d) Remain unchanged in size
Ans. (b)
18. Which of the following statements is not true?
(a) The ratio of the mean speed to the rms speed is independant of temperature
(b) Tthe square of the mean speed of the molecules is equal to the mean squared speed at a certain temperature
(c) Mean kinetic energy of the gas molecules at any given temperature is independant of the mean speed
(d) None
Ans. (b)
19. Which of the following statements represent Raoult,s Law
(a) Mole fraction of solvent = ratio of vapour pressure of the solution to vapour pressure of the solvent
(b) Mole fraction of solute = ratio of vapour pressure of the solution to vapour pressure of the solvent
(c) Mole fraction of solute = lowering of vapour pressure of the solution
(d) Mole fraction of solvent = lowering of vapour pressure of the solution
Ans. (a)
20. Elements having the same atomic number and the same atomic mass are known as
(a) Isotopes
(b) Isotones
(c) Isomers
(d) None of the above
21.Which is the most acidic amongst
(a) Nitrophenol
(b) O-toulene
(c) Phenol
(d) Cresol
22. Pure water does not conduct electricity because it is
(a) Almost not ionised
(b) Low boiling
(c) Neutral
(d) Readily decomposed
Ans. (a)
23. In a salt bridge, KCl is used because
(a) It is an electrolyte
(b) The transference number of K+ and Cl¯ is nearly the same
(c) It is a good conductor of electricity
(d) All of the above
Ans. (d)
24. A depolarizer used in the dry cell batteries is
(a) KCl
(b) MnO2
(c) KOH
(d) None of the above
Ans. (b)
25. The hydrolysis of alkyl halides by aqueous NaOH is best termed as
(a) Electrophylic substitution reaction
(b) Electrophylic addition reaction
(c) Nnucleophylic addition reaction
(d) Nucleophylic substitution reaction
Ans. (d)
26. The hydrocarbon that gives a red precipitate with ammoniacal cuprous chloride is (where ,º, means a triple bond)
(a) CH3-CH2-CH2-CH3
(b) CH3-CºC-CH3
(c) CH2=CH-CH=CH2
(d) CH3-CH2-CºCH
Ans. (d)
27. Which of the following reagents is neither neutral nor basic
(a) Lucas, reagent
(b) Tollen,s reagent
(c) Bayer,s reagent
(d) Fehling,s solution
Ans. (a)
28. The substance which is most easily nitrated
(a) Toluene
(b) Bbenzene
(c) Nitrobenzene
(d) Chlorobenzene
Ans. (a)
29. Carbylamine reaction is a test for
(a) Primary amine
(b) Secondary amine
(c) Tertiary amine
(d) Quarternary ammonium salt
Ans. (a)
30. Which of the following oxides cannot be reduced by carbon to obtain metal
(a) ZnO
(b) Al2O3
(c) Fe2O3
(d) PbO
Ans. (b)
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